Product ID:BENLATE 50 DF FUNGICIDE, DU 002102
MSDS Date:08/01/1990
FSC:6840
NIIN:00N065964
MSDS Number: CBWDC

E I DUPONT DE NEMOURS & CO INC

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-7515

Cage: 0ERJ7

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

2-BENZIMIDAZDECARBAMIC ACID, 1-(BUTYLCARBAMOYL)-, METHYL

CAS: 17804-35-2

RTECS: DD6475000

Fraction By Weight: 50%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3

INERT INGREDIENTS

Fraction By Weight: 50%

OSHA PEL N/K

ACGIH TLV: N/K

BY

RTECS: 9999999ZZ

WAS OBTAINED AT DOSE LEVELS OF 62.5 MG/KG/DAY &

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DISPOSE OF ACCORDING TO APPROVED FEDERAL,

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USING THIS PROD. LABEL INSTRUCTIONS

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LONG SLEEVE SHIRT & LONG LEGGED PANTS;

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BOOTS. WEAR THE FOLLOWING PROT CLTHG DURING

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TO TREATED AREAS BEFORE EXPIRATION OF 24-HR REENTRY

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CHEMICAL RESISTANT GLOVES, SHOES, SHOE COVERING, OR

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ALWAYS WASH HANDS, FACE, & ARMS W/SOAP &

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WORK, TAKE OFF ALL CLOTHES & SHOES. SHOWER USING

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CONTAM CLTHG. WASH PROT CLTHG & PROT EQUIP

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WORN DURING USE MUST BE LAUNDERED SEPARATELY FROM

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DRENCHED W/BENOMYL MUST BE DESTROYED ACCORDING TO

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CANNOT BE ADEQUATELY DECONTAMINATED.

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LD50 LC50 Mixture:LD50 (ORAL RAT): > 5000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAUTION! MAY IRRIT EYES, NOSE,
THROAT & SKIN. MAY CAUSE TEMPORARY ALLERGIC SKIN RXN IN FEW
SUSCEPTIBLE PERS. INGEST: VERY LOW TOX BY INGEST. SKIN: MOD TOX BY
CONT. MALE GUINEA PIG: APPLICATION TO SHAVED SKIN W/FORMULATED
PROD (IN DISTILLED WATER) PRODUCED WEAK SENSIT. EYE RABBIT): MODE
IRRIT. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CORNEAL OPACITY & OTHER EFTS WERE
REVERSED & EYES APPEARED NORM 7 DAYS AFTER EXPOS. CHRONIC STUDIES
(ING 1): FEEDING STUDY (RAT, DOG): IN 2-YR FEEDING STUDIES (W/2500
PPM, HIGHEST DIETARY LE VEL), NO OBSERVABLE EFT LEVEL WAS 2500PPM
FOR RATS & 500 PPM FOR DOGS. IN DOGS FED 2500 PPM, THERE WAS
BIOCHEM (SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. SKIN: IMMED WASH W/SOAP &
WATER. WASH CONTAM CLTHG BEFORE REUSE. EYE: IMMED FLUSH W/PLENTY OF
WATER F OR AT LEAST 15 MINUTES. CALL MD. INGESTION: NO SPECIFIC
INTERVENTION IS INDICATED AS COMPOUND IS NOT LIKELY TO BE HAZARDOUS
BY INGESTION. CONSULT MD IF NECESSARY.

Lower Limits:0.077 G/L
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. EVACUATE PERS TO SAFE AREA. KEEP PERS REMOVED & UPWIND OF FIRE.
COOL TANK/CONTR W/WATER SPRAY.
Unusual Fire/Explosion Hazard:MAY BE IGNITED BY HEAT OR OPEN FLAME.
HAZARDOUS GASES/VAPORS PRODUCED IN FIRE ARE N-BUTYLISOCYANATE.

Spill Release Procedures:REVIEW FIRE AND EXPLOSION HAZARDS AND SAFETY
PRECAUTIONS BEFORE PROCEEDING WITH CLEAN-UP. USE APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. DIKE SPILL. PREVENT
LIQUID FROM ENTERING SEWERS , WATERWAYS OR LOW AREAS. SHOVEL OR
SWEEP UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN, OR
CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. KEEP AWAY FROM HEAT,
SPARKS, AND FLAMES. STORE IN WELL-VENT AREA.
Other Precautions:DO NOT CONSUME FOOD/DRINK/TOBACCO IN AREAS WHERE THEY
MAY BECOME CONTAM W/MATL. KEEP CONTR TIGHTLY CLSD. NEVER ALLOW PROD
TO BECOME WET DURING STOR. THIS MAY LEAD TO CERTAIN CHEM CHANGES
WHICH WILL RE DUCE EFFECTIVENESS OF PROD AS FUNGICIDE.

Respiratory Protection:WEAR A DUST MASK OR A RESPIRATOR APRPOVED BY
NIOSH/MSHA WHEN MIXING OR LOADING FOR AERIAL APPLICATION.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
END USERS OF THIS PROD SHOULD FOLLOW LABEL INSTRUCTIONS WHEN (ING
6)
Work Hygienic Practices:WASH THORO AFTER HNDLG. WASH CLTHG AFTER USE.
IMPORTANT: BEFORE REMOVING GLOVES, WASH THEM W/SOAP & WATER. (ING
11)
Supplemental Safety and Health
HAZ DECOMP PROD: LEVELS &/HIGH TEMPS CAN ALSO LEAD TO GENERATION OF
N-BUTYL ISOCYANATE. EFTS OF OVEREXP: EVIDENCE OF LIVER CIRRHOSIS.
IN 2-YR FEEDING STUDY W/MICE, NO-OBSERVABLE EFT LEVEL WAS 500 PPM
EXCEPT FOR CHANGES IN LIVER. ONCOGENIC EFTS WERE OBSERVED IN LIVERS
OF MALE & FEMALE MICE AT ALL DIETARY LEVELS (ING 3)

Solubility in Water:DISPERSIBLE
Appearance and Odor:CREAM COLORED SOLID, NO ODOR

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMP W/HEAT. HAZ GASES/VAPS PRODUCED
ARE N-BUTYL ISOCYANATE, A STRONG LACHRYMATOR. HIGH
HUMIDITY/MOISTURE (SUP DAT)

Waste Disposal Methods:TREATMENT, STOR, TRANSPORTATION & DISP MUST BE
I/A/W APPLIC FED, STATE, & LOC REGS. REMOVE NONUSABLE SOLID MATL
&/CONTAM SOIL, FOR DISP IN APPRVD & PERMITTED LANDFILL. DO NOT
FLUSH TO SURF WATER/SANIT ARY SEWER SYS. DO NOT REUSE CONTR. (ING5)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.